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Beilstein J. Org. Chem. 2016, 12, 5–15, doi:10.3762/bjoc.12.2
Graphical Abstract
Figure 1: Selected classical and heterogeneous ruthenium complexes.
Figure 2: Applications of NHC ammonium-tagged catalysts.
Scheme 1: Synthesis of ammonium-tagged complex 8.
Scheme 2: Model RCM reaction.
Figure 3: Influence of temperature and concentration on RCM of 9. Conditions: 1 mol % of 8-C* (5 wt % on C*),...
Figure 4: Presentation of various Ru-based catalysts. From the left: 20 mg of Gre-II powder, 20 mg of 8 as fi...
Figure 5: Influence of the support type on the metathesis outcome. Conditions: 1 mol % 8, toluene 80 °C; [9] ...
Figure 6: Filtration of the reaction mixture after RCM of 9 catalysed by 1 mol % of 8-powder.
Figure 7: Split test during RCM of 9 (1 mol % cat, toluene 80 °C, [9] = 0.2 M). The reaction mixtures were fi...
Scheme 3: Model metathesis reactions used in tests.
Figure 8: RCM of 9 catalysed by 8 and 8-Fe. Conditions: 1 mol % catalyst, toluene 80 °C, [9] = 0.2 M.
Figure 9: Removal of 8-Fe and subsequent recovery of 8. A: stirred reaction mixture containing 8-Fe, B: the s...
Scheme 4: Supported catalyst 8 in sequential cross metathesis and reduction.
Beilstein J. Org. Chem. 2015, 11, 1458–1468, doi:10.3762/bjoc.11.158
Figure 1: Selected ruthenium-based complexes.
Scheme 1: trans–cis Isomerization.
Scheme 2: Synthesis of the ligand precursors.
Scheme 3: Synthesis of the ruthenium complexes.
Figure 2: ADPs (atomic displacement parameters) and atoms labeling of the first molecule in the asymmetric pa...
Figure 3: Superposition of the asymmetric parts of units’ cells in both investigated structures: an example o...
Figure 4: Energy profile of trans–cis isomerization, modelled in CH2Cl2, (ΔE in kcal/mol). Geometry optimizat...
Scheme 4: Possible reaction pathways of 16.
Figure 5: Time/conversion plots for the transformation of 16 catalyzed by 5 mol % of the trans isomers of tra...
Figure 6: Composition of a reaction mixture after subjecting 16 to 5 mol % cis-5a in xylene, 140 °C. Lines ar...
Figure 7: Monomers utilized in model ROMP reactions.
Figure 8: Number-average molecular weight (Mn) of poly-21 prepared with initiators 5a, 14 and 15 plotted agai...
Figure 9: STA analysis of polymerization of 22 (left) and 23 (right), initiated by 5a, 14 and 15. Reaction co...